Yes, you can. In their portraits are two symbols-one with a pair of people and one with their icon for work or school. Click on the people and you'll get the usual options of make friends, work hard, slack off, etc. Same goes for Sims at work.
Can anyone confirm if your child actually creates a relationship with other actual sim children while they are at school? Kids that they can text or invite over?
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But meet kid-sims? I don't think so.
Correct me if I am wrong.